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Wednesday, April 14, 2010

Humic Substances, Part 3: History

HISTORY


The term "humus" originates from the Romans, when it was familiarly used to signify the entire soil. Later the term was used to denominate soil organic matter and compost or for different parts of this organic matter, as well as for complexes created by chemical agent treatments to a wide palette of organic substances. The principal definition of humus, as decomposed organic matter, originates from 1761 (Stevenson 1982).

The first relevant study of the origin and chemical nature of HS was worked out by Sprengel (1839). His comprehensive study on the acidic nature of HAs is thought to be his most important benefit to humus chemistry. Research on the chemical properties of HS was extended by the Swedish researcher Berzelius, whose main contribution was the isolation of two light-yellow- coloured HS from mineral water and slimy mud rich in iron oxides (Berzelius 1839).

Enormous advances have been made during the last decade thanks to modern physicochemical methods. Nevertheless, the structural chemistry of lignin and HS did not advance so fast as the chemistry of animal-originated biopolymers.

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